1. Characteristics of TTO series
TTO series are ultra-fine TiO2 products whose particle size is below 100nm.
TTO series can achieve excellent transparency and UV-shielding capability. (Click here for transparency of TTO series.)
When applying for metallic paints, viewing color is varied due to the light scattering ability which is characteristics of ultra-fine TTO. (Click here for flip-flop effects.)
Physically and chemically stable due to the rutile crystal.
Various grades are available depending on the particle size, manufacturing methods and surface treatment.
Major applications
sunscreen cosmetics, automotive paint, toner additives, etc.
2. Comparison of particle size
3. TTO grade variation
| Wet process | |||
| TiO2 | Fe doped TiO2(Beige-colored) | TiO2 | |
| large* | TTO-F-6 | TTO-D series | |
| medium | TTO-55 series |
TTO-F-2 |
|
| small | TTO-51 series | TTO-S
series
MPT-135,136 |
|
| very small | TTO-V series | ||
* Larger particle grades are under development.
1. TTO-51,55 series (Calcination process)
| TTO-51(A) | TTO-51(C) | TTO-55(A) | TTO-55(B) | TTO-55(C) | TTO-55(D) | |
| Crystal form |
Rutile |
|||||
| TiO2% | 76-83 | 79-85 | 93-98 | 88-94 | 86-92 | 74-81 |
| Surface treatment | Al(OH)3 | Al(OH)3 / stearic acid | Al(OH)3 | Al(OH)3 | Al(OH)3 / stearic acid | ZrO2 / Al(OH)3 |
| OA(g/100g) | 40-47 | 24-30 | 27-34 | 29-38 | 17-24 | 35-45 |
| SSA(m2/g) | 75-85 | 50-60 | 35-45 | 35-45 | 25-.35 | 65-85 |
| Particle size(μm) | 0.01〜0.03 | 0.01〜0.03 | 0.03-0.05 | 0.03-0.05 | 0.03-0.05 | 0.03-0.05 |
| Surface property | hydrophilic | hydrophobic | hydrophilic | hydrophilic | hydrophobic | hydrophilic |
| TEM |
0.1μm |
0.1μm |
||||
2. TTO-S、V series (Wet process)
| TTO-S-1 | TTO-S-2 | TTO-S-3 | TTO-S-4 | MPT-136 | TTO-V-3 | TTO-V-4 | |
|
Rutile |
|||||||
| TiO2(%) | 84-92 | 77-86 | 80-87 | 78-84 | 71-77 | 80-90 | 68-74 |
| Crystal form | ZrO2 / Al(OH)3 | ZrO2 / Al(OH)3 / stearic acid | Al(OH)3 | Al(OH)3 / stearic acid | Al(OH)3 / stearic acid | Al(OH)3 | Al(OH)3 / stearic acid |
| OA(g/100g) | 46-56 | 37-47 | 52-62 | 19-39 | 21-25 | 40-60 | 25-35 |
| SSA(m2/g) | 90-110 | 55-80 | 85-105 | 52-72 | 40-60 | 120-150 | 60-80 |
| Particle size(μm) |
width 0.01-0.02 length 0.05-0.1 |
width 0.01-0.02 length 0.05-0.1 |
← | ← |
width 0.01-0.02 length 0.05-0.1 |
width 0.005-0.015 length 0.03-0.09 |
← |
| Surface property | hydrophilic | hydrophobic | hydrophilic | hydrophobic | hydrophobic | hydrophilic | hydrophobic |
| TEM |
0.1μm |
0.1μm |
0.1μm |
||||
3. TTO-F series (Fe modified ultra-fine TiO2, beige-colored)
| TTO-F-2 | TTO-F-6 | |
| Crystal form |
Rutile |
|
| TiO2% |
82-90 |
|
| Surface treatment |
Al(OH)3 |
|
| OA(g/100g) | 32-42 | 30-40 |
| SSA(m2/g) | 40-55 | 30-40 |
| Particle size(μm) | 0.03-0.05 | 0.05-0.09 |
| Surface property | hydrophilic | hydrophilic |
4. Neutral Titania Sol “TTO-W-5”
TTO-W-5 is highly transparent and stable aqueous titania sol of rutile type TiO2, treated with silica on the surface.
| Appearance | White liquid |
| Crystal form |
Rutile |
| TiO2% |
ca. 30 |
| Surface treatment |
SiO2 |
| pH | 6.0-8.0 |
| Viscosity(mPa・s) | 50 max. |